We report the properties of CsCaCl
3, storage phosphors doped with Eu, Ce, or Cu. Both doped and undoped CsCaCl
3 samples were synthesized as ceramics. For undoped CsCaCl
3, thermally stimulated luminescence (TSL) spectrum showed a broad band around 360–390 nm, and optically stimulated luminescence (OSL) spectrum exhibited the same band with a shoulder near 320 nm. These bands were attributed to different kinds of defects or impurities. The OSL and TSL spectra of Eu-doped CsCaCl
3 showed a band around 440 nm arising from the 5d–4f transition of Eu
2+. The Ce-doped CsCaCl
3 showed the OSL and TSL bands originating from the 5d–4f transition of Ce
3+. An intense band at 345 nm appeared in the OSL spectrum of Cu-doped CsCaCl
3 due to Cu
+, and an additional peak at 430 nm was ascribed to Cu
+ ion perturbed by OH
− ion. On the other hand, the TSL spectrum of Cu-doped CsCaCl
3 had a peak around 470 nm and it was assigned to Cu
2+. The TSL glow curves of the undoped, Eu-doped, Ce-doped, and Cu-doped CsCaCl
3 were different from each other. This suggested that the dopant ions influenced the trapping process of electron–hole pairs, which were formed upon irradiation.
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