Journal of Chemical Software
Online ISSN : 1883-8359
Print ISSN : 0918-0761
Original Papers
Visualization of Electrochemical Measurements under Finite Conditions using JAVA and Its Application for Assisted Learning (2)
Hidenobu SHIROISHIToshifumi SHOJITomoyo NOMURASumio TOKITAMasao KANEKO
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2002 Volume 8 Issue 2 Pages 41-46

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Abstract

A program written in JAVA language was developed for the virtual electrochemical measurement of a modified electrode with a finite diffusion thickness, e.g., an electrode coated with polymer film in which functional molecules were dispersed. This program, called ES-2, can simulate cyclic voltammetry and potential-step chronoamperospectrometry by considering the rate of charge injection from the electrode to the functional molecule and the diffusion of charge. The results are shown by a voltammogram (I-V curve), and concentration distribution in the layer at a series of voltages at cyclic voltammogram mode, I-t curve, and time dependence of concentration distribution in the layer at potential step mode and a text of current values, the fraction of the oxidized molecules (RCT) and parameters used for the simulation in both modes. A dynamic textbook of electrochemistry can be constructed by this program combined with HTML text.

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© 2002 by the Chemical Software Society of Japan
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