アミン類を主剤とする防食剤の研究 (第16報)
側鎖を有する炭化水素基の影響-その2
1960 年 9 巻 1 号 p. 6-9
詳細
1960 年 9 巻 1 号 p. 6-9
Amine-type corrosion inhibitors with branched alkyl radicals were tested. Less inhibition was given with those whose side chains were at nearer position to adsorbents and better inhibition with those whose side chains were more remote. The side chains attached nearer, interfered inner-molecularly with the adsorbents, and remote ones promoted inhibition because of its affinity to the solvent. But, some remote branches inter-molecularly interfered with orientation of inhibitors to metal surfaces as known steric effects in organic chemistry.
