Corrosion Engineering
Online ISSN : 1881-9664
Print ISSN : 0917-0480
ISSN-L : 0917-0480
The Study on the State of Hydrogen Dissolved in Metals by Means of the Channelling Method
Eiichi Yagi
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2000 Volume 49 Issue 5 Pages 282-287

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Abstract
The lattice locations of hydrogen dissolved in V, Nb, Ta and Nb-Mo alloys are investigated by the channelling method utilizing a nuclear reaction 1H(11B, α) αα with a 11B beam. The H atoms are located at tetrahedral (T) sites in V, Nb and Ta. In V, under the [001] compressive stress of 7 kg/mm2, the H atoms are displaced from T sites by about 0.44Å towards octahedral (O) sites, and after the release of the stress they return to the T sites. In Nb-3 at%Mo alloys the H atoms are located at the sites displaced from the T sites by about 0.6Å towards the nearest neighbour lattice points at room temperature and become located at the T sites at 373K, indicating the trapping of H by Mo atoms at room temperature. With increasing Mo concentration, the fraction of the H atoms located at the trapped sites decreases, and most of them are located at the T sites and some portion of them are at the O sites.
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