In order to shorten the Esp measurement period, the potential of four types of stainless steel pipes in an 80℃ hot water environment containing R-Cl was measured using the R-Cl concentration as a parameter. As a result, an approximate linear equation was obtained that shows the relationship between Esp and R-Cl concentration. Because the obtained potential data and the slope of the linear approximation equation were close to published and estimated values, it is believed that Esp can be calculated from the approximate linear equation obtained this time when the usage environment is close to the test conditions used in this study.
In sulfate- or chloride-ion environments, the current density in the active/passive transition region in Fe-11 mass% Cr steels decreases with the addition of 2 mass% Al or Si. This reduced current density lowers the passivation pH; consequently, the corrosion resistance of the Al/Si-added Fe-11 mass% Cr steel is superior to that of the Fe-11 mass% Cr steel. The Al (or Si) content in the passive film formed on Fe-11 mass% Cr-2 mass% Al (or -2 mass% Si), is higher than that in the substrate. The excellent corrosion resistance of the Al-added low-Cr stainless steel is attributed to the generation of Al(III) hydroxides, which dominates over that of Fe(II) and Cr(III). By contrast, the excellent corrosion resistance of the Si-added low-Cr stainless steel is ascribed to the formation of Si oxides.