Corrosion Engineering
Online ISSN : 1881-9664
Print ISSN : 0917-0480
ISSN-L : 0917-0480
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  • Masatoshi Abe, Akinori Kawano, Toru Matsuhashi, Nobuhiko Hiraide, Jun- ...
    2025Volume 74Issue 8 Pages 155-164
    Published: August 10, 2025
    Released on J-STAGE: September 25, 2025
    JOURNAL FREE ACCESS

    In sulfate- or chloride-ion environments, the current density in the active/passive transition region in Fe-11 mass% Cr steels decreases with the addition of 2 mass% Al or Si. This reduced current density lowers the passivation pH; consequently, the corrosion resistance of the Al/Si-added Fe-11 mass% Cr steel is superior to that of the Fe-11 mass% Cr steel. The Al (or Si) content in the passive film formed on Fe-11 mass% Cr-2 mass% Al (or -2 mass% Si), is higher than that in the substrate. The excellent corrosion resistance of the Al-added low-Cr stainless steel is attributed to the generation of Al(III) hydroxides, which dominates over that of Fe(II) and Cr(III). By contrast, the excellent corrosion resistance of the Si-added low-Cr stainless steel is ascribed to the formation of Si oxides.

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