日本結晶学会誌
Online ISSN : 1884-5576
Print ISSN : 0369-4585
ISSN-L : 0369-4585
特集 結晶学とグラフ
氷の高次構造と均衡原理
松本 正和 二井矢 圭佑田中 秀樹
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ジャーナル フリー

2024 年 66 巻 1 号 p. 39-47

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As a simple consequence of the ice rule, we propose the balance principle of ice, which states that the numbers of inward and outward hydrogen bonds across any closed surface inside ice satisfying the ice rule are equal. The equilibrium principle clearly explains the effects of polarization and defects in ice. It can also be inferred that the phase transition between hydrogen-ordered ice and hydrogen-disordered ice differs from the transition between the normal ordered and disordered phases.

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