ビイミダゾール型分子間水素結合を利用した金属錯体のクリスタルエンジニアリング
2003 年 45 巻 4 号 p. 240-248
詳細
2003 年 45 巻 4 号 p. 240-248
Manipulation of molecular crystals formed from self-organization is one of important methods to develop the new molecular functional materials. We have been looking upon in particular mutual cohesive interactions of hydrogen bonding and metal coordination as one of useful tools to construct the preprogramming super-structures. In this study, four controlled super-structures of a one-dimensional linear chain, a zig-zag ribbon, right-handed and lefthanded helices, and a two-dimensional honeycomb sheet are newly created by using the neutral metal complexes with some 2, 2'-biimidazolate mono-anions.
