単結晶中性子回折を用いた結晶相反応の直接観察
2008 年 50 巻 1 号 p. 98-102
詳細
2008 年 50 巻 1 号 p. 98-102
The exchange of some hydrogen atoms with the other hydrogen atoms in the crystallinestate reactions, in which the reaction proceeds with retention of the single crystal form, can be directly observed by single crystal neutron diffraction technique if only the transferred hydrogen atoms were replaced with deuterium atoms before the photoirradiation. The method was successfully applied in the photoisomerization of three kinds of cobalt complex crystals and the mechanism in each reaction has been made clear.
