Clay Science
Online ISSN : 2186-3555
Print ISSN : 0009-8574
ISSN-L : 0009-8574
INFLUENCE OF SYNTHESIS CONDITIONS ON MESOSTRUCTURE OF CERIA-CLAY COMPOSITE AND ITS CATALYTIC COMBUSTION OF METHANOL
TERUHISA HONGODAISUKE TAKASHIMASHOTA UMEHARASHIGEO SATOKAWAAKIHIRO YAMASAKI
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JOURNAL FREE ACCESS

2012 Volume 16 Issue 3 Pages 89-93

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Abstract
Ceria-clay composite was prepared using a nonionic poly(ethylene oxide) surfactant. The preparative conditions with regard to the surfactant amount and calcination temperature were changed, to study their effects on the mesostructure of the ceria-clay composite. The specific surface area, pore diameter, and pore volume increased with increasing surfactant amount. The calcination temperature had little influence on the mesostructure up to 650℃, but the structure collapsed above 750℃. The crystallite size of ceria, estimated using the Scherrer's method, decreased with increasing surfactant amount, and increased with increasing calcination temperature above 750℃. The ceria-clay composite catalyzed the complete combustion of methanol at 300℃.
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© 2012 The Clay Science Society of Japan
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