Clay Science
Online ISSN : 2186-3555
Print ISSN : 0009-8574
ISSN-L : 0009-8574
THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF A J-AGGREGATED CYANINE DYE INTERCALATED IN SAPONITE
YASUTAKA SUZUKIYUTA TENMAYUKIHIRO NISHIOKAMAKOTO TOMINAGASEIJI TANIJUN KAWAMATA
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2013 年 17 巻 2 号 p. 41-45

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We fabricated low-light-scattering hybrid films consisting of synthetic saponite and 1,1'-diethyl-2,2'-cyanine (PIC). J-aggregation of PIC was observed for the hybrid films at high PIC loadings. Two-photon absorption (TPA) and third harmonic generation (THG) properties have been compared between two hybrid films fabricated at 10 and 80% CEC PIC loadings. As a result, the TPA cross-section and THG intensity of PIC in 80% CEC hybrid films were 1.8 and 1.6 times, respectively, larger than those in the film fabricated at 10% CEC. These enhancements were attributed to formation of J-aggregation of PIC in the 80% CEC hybrid film.
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© 2013 一般社団法人 日本粘土学会
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