Clay Science
Online ISSN : 2186-3555
Print ISSN : 0009-8574
ISSN-L : 0009-8574
PARTICLE-PARTICLE AND PARTICLE-WATER INTERACTIONS IN AQUEOUS CLAY SUSPENSIONS. PART I. APPLICATION OF A MODIFIED ROBINSON EQUATION TO VISCOSITY DATA
KOJI WADAYOSHIKAZU NITAWAKIKAZUHIKO EGASHIRA
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1981 年 5 巻 6 号 p. 313-318

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The Robinson equation was modified and applied to the viscosity data of clay suspensions to which the Einstein equation was not applicable. The modified Robinson equation is:
ηrel-1=k'S'V/(1-S'V) where ηrel is the relative viscosity, V the volume concentration of clay particles (cm3/cm3), S' a parameter for the ratio of the effective volume of clay particles to their actual volume and k' another parameter related to particle-particle interaction. The S' value increased from about 10 for spherical halloysite suspensions to allophane, kaolinite, montmorillonite and up to 1900 for fibrous imogolite suspensions. The k' value increased from about 1 for deflocculated suspensions to 20 for flocculated suspensions.
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