粘土科学
Online ISSN : 2186-3563
Print ISSN : 0470-6455
ISSN-L : 0470-6455
溶融技術による土壌等からのセシウム熱分離に関する試験研究及びFS評価(<シンポジウム特集>粘土とセシウム)
阿部 清一釜田 陽介川本 克也倉持 秀敏大迫 政浩
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2015 年 54 巻 1 号 p. 43-53

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Melting technique is one of useful high-temperature treatments carried at 1300-1400℃. Using the technique, Cs can be separated in high efficiency from different solids degreasing their volume significantly. In our previous laboratory melting test, a high Cs volatilization ratio had been obtained for various solid wastes containing non-radioactive Cs. Therefore, in this study, we conducted a demonstration plant test (3 t/day) for soil, biomass incineration ash, etc. containing non-radioactive Cs. As a result, regardless of the kind of solid sample, Cs volatilization ratio increased by the addition of CaCl_2 even in the plant scale test. The Cs volatilization ratio in the presence of combustible vegetation was higher than that without the combustibles. Increasing the amount of additive reagent and vegetation achieved 99.9% of the Cs volatilization ratio. Next, we conducted a laboratory melting test for soil containing radioactive Cs. As a result, the volatilization ratio of radioactive Cs with the addition of CaCl_2 was the almost same as that of non-radioactive Cs, this shows the influenced factor by the addition of CaCl_2 was not the volatilization amount of Cs but the gas-liquid distribution ratio of Cs. Furthermore, we carried out a feasibility study on applying the melting technique to the treatment of decontamination wastes. As a result, it was estimated that total 30 years' cost (from intermediate treatment to final disposal) was the lowest in the case of applying the melting technology to the treatment of only fine soil and the ash of combustibles.

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