Structure of Clay Minerals/Organic Polymers Inclusion Compounds

Yoshiaki FUKUSHIMA

doi:10.11362/jcssjnendokagaku1961.30.143

Journal of the Clay Science Society of Japan (in Japanese)

Online ISSN : 2186-3563
Print ISSN : 0470-6455
ISSN-L : 0470-6455

Structure of Clay Minerals/Organic Polymers Inclusion Compounds

Yoshiaki FUKUSHIMA

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Keywords: inclusion, intercalation, structure, smectite, montmorillonite, sepiolite, polymerization, nylon, swelling, interlayer cation

JOURNAL FREE ACCESS

1990 Volume 30 Issue 2 Pages 143-147

DOI https://doi.org/10.11362/jcssjnendokagaku1961.30.143

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Abstract

Polymerization reaction of εA-caprolactam initiated at an interlayer spacing of smectite and the structure of the obtained intercalated compounds were reviewed. Characteristics of clay minerals as a host for intercalation or inclusion; functions of interlayer cations, swelling behaviour, layer charge distribution, two dimentional character of silicate layers, and reactions at crystal edges of layers, were discussed.

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