燃料協会誌
Online ISSN : 2185-226X
Print ISSN : 0369-3775
ISSN-L : 0369-3775
石炭のコークス化過程における脱硫
昭和44年10月2日石炭科学会議講演
長谷部 新次常本 武竹下 健次郎有田 静児
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1969 年 48 巻 12 号 p. 892-899

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Some reagents were added to two kinds of coals, “Miike” and “Matsushima” in order to remove the sulfur during carbonization.
As a sources of active hydrogen, tetraline, isopropyl alcohol and cyclohexane were used.
At the temperature of 500-600°C, tetraline was more effective than hydrogen, to remove the sulfur from coal, but it was not so effective at the temperature higher than 700deg;C.
After converting the organic sullfur to inorganic one, they were washed with water, aqueous acids or alkalines.
Some of Fe-compounds, for example Fe (OH) 3, FeCl2, FeCl3, K4Fe (CN) 6 etc., were also used in Matsushima coal and the mixtures were carbonized at 750deg;C, but it is not so practical.
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