燃料協会誌
Online ISSN : 2185-226X
Print ISSN : 0369-3775
ISSN-L : 0369-3775
2-ニトロソ-1-ナフトール-4-スルホン酸による湿式酸化脱硫法
内田 洋津留 義通河田 達也寺崎 太二郎小島 幸井筒 和一郎
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1981 年 60 巻 1 号 p. 58-64

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The liquid redox desulfurization using 2-nitroso-1-naphthol-4-sulfonic acid as redox catalyst has been studied by a stirred vessel, a laboratory apparatus and a pilot for 2, 000 Nm3/hr coal gas.
The experimental results indicated that this redox catalyst has high activity and selec-tivity to thiosulfate. Particularly, on the pilot plant for 2, 000 Nm3/hr coal gas, 1 mol/m3 of 2-nitroso-1-naphthol-4-sulfonic acid obtained the same desulfurization coefficiency as 2 mol/ma of ammonium 1, 4-naphthoquinone-2-sulfonate. Accordingly, for the liquid redox desulfuriza-tion where no sulfur is deposited in the solution, it is more excellent than the earlier organic catalysts such as ammonium 1, 4-naphthoquinone-2-sulfonate.

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