19.微粉炭燃焼フライアッシュ中の炭素分の性状

抄録

Fly ashes E and G those discharged from a same pulverized coal combustion boiler were classified into two components, such as smaller fly ash particle under 38μm and larger fly ash particle above 125μm. The carbon contained in both components were separated from fly ash by using the Ultrasonic Oil Agglomeration method. Properties of separated carbons were investigated by applying the X-ray diffraction, SEM (Scanning Electron Microscope) and TGA (Thermogravimetric Analysis). Following results are obtained. (1) The carbon remains in the larger fly ash as the unburned char, and that contained in smaller fly ash are carbon black and rock carbon. (2) Significant differences of the carbon contents and their properties between the fly ashes E and G are found. The carbon content in smaller components of fly ash G is fairly greater than that in smaller components of fly ash E, although the coal G shows a good combustibility. These observations of the properties of carbon containing in fly ash present significant Informations on the for rational operation and control in the process of pulverized coal combustion process.