石炭科学会議発表論文集
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
第31回石炭科学会議
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18.石炭液化反応のC-C結合切断における水素移行過程のモデル物質による検討
佐古田 隆仁松井 隆雄大野 浩司池永 直樹鈴木 俊光
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p. 71-74

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Cracking of dinaphthylethane in 9,10-dihydrophenanthrene and diphenylethane in tetralin in the absence or in the presence of dispersed catalysts such as Mo-S and Ru was studied under hydrogen atmosphere. The amounts of hydrogen transferred from a gas phase and a donor solvent were determined and the amounts of hydrogen required to stabilize free radicals derived from the model compound were estimated from the products distributions. Most of the hydrogen required to stabilize free radicals seemed to come from the hydrogen donor solvent, even in the presence of an active catalyst.

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© 1994 一般社団法人 日本エネルギー学会
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