石炭科学会議発表論文集
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
第33回石炭科学会議
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3.液化溶剤の改良研究 : 石炭液化油の軽質化と触媒添加量の低減
奥山 憲幸安室 元晴佐藤 光一小松 信行奥井 利明嶋崎 勝乗
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p. 9-12

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Effects of heavy solvent (bp.300-420℃) recycling and partial pressure of H_2S with iron/sulfur catalysts on coal liquefaction were investigated using bench scale unit (BSU). Process operations such as gas recycling and CLB (bp.420℃+) recycling were effective to increase distillate (C_5〜420℃) yield. It was confirmed that applying heavy solvent recycling to the operations, content of lighter fraction in product distillate was increased in maximum distillate yield of Victorian brown coal over than 60%mafc. Furthermore, it was proved that the amount of catalyst addition could be reduced to 1% by using γ-FeOOH as catalyst with excess sulfur to keep suitable partial pressure of H_2S in reactors.

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© 1996 一般社団法人 日本エネルギー学会
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