主催: 社団法人 日本エネルギー学会
共催: 社団法人 化学工学会 エネルギー開発特別研究会
会議名: 第36回石炭科学会議
回次: 36
開催地: 船橋市
開催日: 1999/10/28 - 1999/10/29
p. 423-426
We have investigated the development of coal liquefaction process through partial oxidation in supercritical water. In this study, we conducted hydrodenitrogenation of calbazole via water-gas shift reaction in supercritical water and partial oxidation of n-hexadecane in supercritical water using a tube bomb batch reactor. For hydrodenitrogenation of calbazole, the yield of tetrahydrocarbazole and denitrogenated compounds at 0.3g/cm^3 of water density was higher than that at lower water density, except for 0.05g/cm^3 of water density. The yield of unknown product, which was seemed to be higher molecular weight compound, was suppressed in supercritical water. For partial oxidation of n-hexadecane in supercritical water, the relative amount of oxygenated compounds, which were CO, aldehydes, and ketones, increased with increasing water density. The relative amount of n-alkane also increased with increasing water density.