主催: 社団法人 日本エネルギー学会
共催: 化学工学会 (エネルギー開発特別研究会)
後援: 日本ガス協会
会議名: 第37回石炭科学会議
回次: 37
開催地: 札幌サンプラザ
開催日: 2000/09/28 - 2000/09/29
p. 233-236
Metal compositions of Ni containing Soroako limonite in Indonesia were characterized by using TG, XRD, TEM-EDX and XPS in relation to the catalytic activities in direct coal liquefaction. It appeared that α-FeOOH and Al(OH)_3 were dominant species in Soroako limonite and very fine particles of Fe_<1-X>S were formed by the addition of elemental sulfur at 300℃. The crystal growth of Fe_<1-X>S may be suppressed by some interactions such as Fe-O-Al, leading to the high liquefaction activity. Results of TEM-EDX analysis suggest that Ni may locate near Fe_<1-X>S species, which is recognized as an active phase in coal liquefaction.