石炭科学会議発表論文集
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
第45回石炭科学会議
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78 固体炭素系資源の熱分解に関する活性化エネルギー分布と補償効果(熱分解・コークス(3))
園山 希林 潤一郎
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p. 156-157

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Pyrolysis characteristics of various biomass species were investigated with a thermogravimetric analyzer. Kinetic parameters that are activation energies and pre-exponential factors obtained by the Miura method changed dramatically during pyrolysis process. There was the case that kinetic parameters decrease with an increase in conversion for biomass pyrolysis, while activation energy for coal increases with increasing conversion. The decrease in kinetic parameters was caused by structural changes derived from softening, depolymerization, solidification and so on. Kinetic parameter distributions were available to the characterization of biomass pyrolysis.

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© 2008 一般社団法人 日本エネルギー学会
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