主催: 社団法人 日本エネルギー学会 石炭科学部会, 社団法人 日本エネルギー学会 コークス工学研究部会
共催: 化学工学会 エネルギー部会, 日本エネルギー学会 重質油部会, 京都大学大学院 工学研究科
会議名: 第45回石炭科学会議
回次: 45
開催地: 京都大学 百周年時計台記念館
開催日: 2008/10/09 - 2008/10/10
p. 68-69
Fe and Ni catalysts supported on a Canadian peat-derived, H_3PO_4-activated carbon are characterized by several methods, and their performance in NH3 decomposition is investigated with a fixed bed quartz reactor from a viewpoint of hot gas cleanup. The X-ray photoelectron spectroscopy (XPS) analysis of the fresh catalysts after calcination at 500℃ reveals the significant retention of P on their surfaces, whereas the X-ray diffraction (XRD) measurements show the absence of any diffraction lines of Fe species and the appearance of metallic Ni. Both catalysts remarkably promote the decomposition of 2000ppm NH_3 diluted with inert He at 750℃ and show high, stable NH_3 conversions to N_2 of 75-90%. Because Fe and Ni phosphides are detectable by the XRD after the reaction, these species might be catalytically active.