主催: 日本エネルギー学会 石炭科学部会, 日本エネルギー学会 コークス工学研究部会
共催: 日本学術振興会 石炭・炭素資源利用技術第 148 委員会, 化学工学会 エネルギー部会, 重質油部会, ガス化部会, 燃焼部会
会議名: 第54回石炭科学会議
回次: 54
開催地: 秋田ビューホテル
開催日: 2017/10/18 - 2017/10/19
p. 22-23
To develop a mild chemical desulfurization method without residual chemicals in the treated Hyper-coal, desulfurization behavior was investigated by oxidation using hydrogen peroxide and acetic anhydride at room temperature and by pyrolyzing the treated sample under nitrogen stream. XANES analysis showed that the Hyper-coal contained only thiophenic sulfur and that the thiophenic sulfur changed to sulfone during the oxidation treatment. High removal extent of sulfur with high char yield was achieved by pyrolyzing the oxidized sample prepared at room temperature for 24 hour.