石炭科学会議発表論文集
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
第55回石炭科学会議
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改質・処理・クリーン化(2),灰・微量元素(1),その他(1)
No.1-13 石炭火力発電副産物中の水銀の存在形態
作左部 皓輔加藤 貴宏大川 浩一菅原 勝康
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会議録・要旨集 フリー

p. 26-27

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Mercury forms in fly ash and desulfurization gypsum produced from the coal-fired power plant were analyzed. A combination of temperature programmed desorption (TPD) and cold vapor atomic absorption spectrometry (CVAAS) was applied and the optimum operating condition was determined to clarify the forms of mercury. TPD curves of mercury obtained for the ash and gypsum were analyzed qualitatively and quantitatively with comparing to the peak temperature and linear combination of TPD curves of model mercury compounds. The results indicated that mercury in the desulfurization gypsum was mainly composed of HgCl2 and the adsorbed one by unburned carbon.

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