石炭科学会議発表論文集
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
第55回石炭科学会議
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自然発熱(2)
No.2-3 石炭の低温における自然発熱の速度解析
三浦 孝一Janewit Wannapeera大垣 英明
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p. 52-53

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Temperature increase of dried brown coal packed in a small tube reactor was measured in the gas stream of either wet air or dry air. The reactor was placed in a temperature controlled air circulating oven. In the wet air stream big temperature increase was observed even at 50 °C of oven temperature, whereas the temperature increase was very small in dry air even at 110 °C of oven temperature. The temperature changes of coal bed with time and position of the reactor were well simulated by simple one-dimensional energy and mass balance equations. Simulation in a wet air stream at 70 °C of oven temperature under adiabatic condition showed spontaneous heating of coal leading to combustion, showing that the spontaneous combustion is caused by simultaneous effects of water vapor adsorption and air oxidation.

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