石炭科学会議発表論文集
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
第56回石炭科学会議
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熱分解・コークス、自然発熱
1-22 石炭熱分解時の芳香族クラスター成長により発生する水素の転換反応機構
福岡 鉄也Cheolyong CHOI町田 洋則永 行庸
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p. 44-45

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Changes in chemical structure of coal during carbonization are important factors to determine properties of softening and melting. It is believed that the caking properties are directly affected by transferable hydrogen, and its consumption lowers the degree of caking. Investigation of the fate of the hydrogen during carbonization is thus necessary for understanding the characteristics of caking. This work conducted quantitative analyses of the chemical structure of coke derived from caking and non-caking coal, together with an online gas analysis. As a result, the transferable hydrogen derived from the non-caking coal was partly consumed for decomposition of the functional groups such as ethers during carbonization, while that from the caking coal was little consumed.

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