石炭科学会議発表論文集
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
第57回石炭科学会議
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灰・微量元素
2-10 空気およびAr雰囲気下での石炭灰分結晶質の熱的挙動解析
石原 篤高井 健太郎橋本 忠範
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p. 38-39

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The thermal behavior of ash components in bituminous coals (Upper Freeport (UF), Illinois #6 (IL) and Beulah-Zap (BZ)) under air and argon atmospheres in the range temperature of 800-1200°C was investigated using XRD and TEM measurements. UF treated under air formed the needle-like crystals which was deduced to be mullite by transformation of andalusite because they mainly consisted of SiO2 and Al2O3. In contrast to UF, IL did not generate these crystals. However, when IL was treated under air after carbonization under Ar, the crystals appeared. The presence of lime in IL inhibited the formation of mullite. Oldhamite was formed by reacting lime with sulfur at the carbonization of IL. As lime was consumed, the formation of mullite was not inhibited under air after Ar treatment.

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