石炭科学会議発表論文集
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
第57回石炭科学会議
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ガス化・燃焼、灰・微量元素
1-03 石炭火力発電所由来フライアッシュ中の水銀の化学形態
ウアシケテ ドルカス リンダ エルネスト作左部 皓輔加藤 貴宏大川 浩一菅原 勝康
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p. 6-7

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An analysis was performed by combining the TPD and CVAAS to identify and quantify the mercury forms in the fly ash produced from a coal-fired power plant. The TPD curve of the model sample for each mercury compound showed a unique peak temperature, and the chemical form of mercury was identified by comparing the peak temperature with that of the fly ash. A linear combination of the TPD curve of each model sample was curve-fitted to that of the fly ash. The calculated results revealed that 45% of total mercury is C-Hg in the fly ash followed by HgO, HgS, HgSO4・2HgO, HgSO4 with around 14%.

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