Proceedings of Conference on Coal Science
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
[volume title in Japanese]
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1-10 Depolymerization of coal by treatment with formic acid vapor in air under mild conditions
Jie RENRyuichi ASHIDAMotoaki KAWASEKoji SAKAINoriyuki OKUYAMA
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CONFERENCE PROCEEDINGS FREE ACCESS

Pages 20-21

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Abstract

We have proposed a novel coal pre-treatment method that combines oxidation reactions by molecular oxygen and the following reduction reactions by coexisting gaseous formic acid to upgrade a bituminous coal at 90°C-150°C under atmospheric pressure. It was found that the softening and melting performance of the treated coals was enhanced when oxygen and formic acid existed in gas phase at the same time at 90‒130°C. The amount of low-molecular-weight compounds (LMWC) in the coal significantly increased by the treatment, increased by 29% on raw coal’s LMWC basis by the treatment at 90°C in oxygen/formic acid. Surprisingly, the oxygen content of the coal decreased even in the presence of molecular oxygen when formic acid coexisted.

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© 2022 The Japan Institute of Energy
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