石炭科学会議発表論文集
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
第59回石炭科学会議
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ガス化・燃焼、改質・処理・クリーン化
2-08 過酸化物を用いた酸化における亜瀝青中硫黄形態の変化
加藤 貴宏Dorcas L. E. UACIQUETE小野寺 凱大川 浩一菅原 勝康Nakorn WORASUWANNARAK
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p. 44-45

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To prepare ultra-low sulfur coal, we have challenged chemical desulfurization of subbituminous coals using two peroxides, hydrogen peroxide and peracetic acid. In the presence of hydrogen peroxide, oxidation was promoted only at 60°C, accompanied by significant carbon loss. On the other hand, treatment with peracetic acid promoted the oxidation of thiophene with low carbon loss. By combining pre-oxidation with peracetic acid treatment and pyrolysis at 400°C, 74% of total sulfur and 72% of thiophene could be removed while recovering approximately 90% of total carbon as char.

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