Journal of Japan Institute of Light Metals
Online ISSN : 1880-8018
Print ISSN : 0451-5994
ISSN-L : 0451-5994
RESEARCH REPORT
Solidus composition in Mg side phase diagram of Mg–Zn binary system and its estimation method
Shin-ya KOMATSUMasahiko IKEDAUmihiko MORI
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2004 Volume 54 Issue 1 Pages 25-30

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Abstract
Eutectically solidified portion, which should be liquid at 673 K, remained in alloys containing more than 7.8 mass% Zn. From change in area fraction of the liquid phase with Zn content, boundary composition between L+α and α regions at 673 K was estimated as about 6.7 mass% Zn. Resistivity of a specimen containing 7.8 to 8.6 mass% Zn increased with descending temperature treatment starting from 673 K and saturated at 633 K. Treatment at 613 K, the reported eutectic temperature, prolonged for 602 ks gave a nearly same saturating resistivity which suggested a maximum equilibrium solubility of Zn to Mg to be about 8.5 mass%. Details to be paid attention are described for resistivity measurement of large cross section specimens requiring a large electric current to generate enough electromotive force. When the resistance was measured in liquid nitrogen, effect of Joule heat was scarcely observed. The heating effect was clearly observed when the resistance was measured in a kerosin bath. Even in this case, the effect can be eliminated easily by extrapolation of square of current versus measured resistance plots to zero current.
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© 2004 by The Japan Institute of Light Metals
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