Journal of Japan Institute of Light Metals
Online ISSN : 1880-8018
Print ISSN : 0451-5994
ISSN-L : 0451-5994
Effect of barrier layer thickness on aqueous corrosion of aluminum
Goro ITOKenjiro GOTOYoshihiko SHIMIZU
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1969 Volume 19 Issue 6 Pages 264-268

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Abstract
Barrier layer thickness of aluminum, which had been subjected to corrosion tests in water containing a few ppm of various reagents, was determined by the polarization method proposed by M. S. Hunter and P. Fowle.
The thickness of barrier layer formed in the air decreased with increasing time of immersion in pure water up to 100hrs. The same behavior was also observed on aluminum tested in water containing any one of NaNO3, NaCl, NaOH, and HCl. While, in water containing any one of NaF, Na2SO4, Na2SiO3, H2SO4, and H3PO4, the thickness of the layer formed in the air once decreased at the initial stage of immersion, and then, began to increase.
These results were compared with the corrosion rate of aluminum tested in the solutions mentioned above.
It was concluded that there was inverse correlation between the corrosion rate of aluminum and the barrier layer thickness after the tests in the various testing solutions for 100hrs. Further studies shall be made in future to reveal the reason of specific effects of anion in testing solutions on the barrier layer thickness of aluminum which was immersed in the solutions.
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© The Japan Institute of Light Metals
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