Journal of the Japan Institute of Metals and Materials
Online ISSN : 1880-6880
Print ISSN : 0021-4876
ISSN-L : 0021-4876
Thermodynamic Properties of Chromium-Carbon System by Electro-motive Force Measurements
Hiroshi TanakaYasuo KishidaAkio YamaguchiJoichiro Moriyama
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1971 Volume 35 Issue 5 Pages 523-527

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Abstract
Thermodynamic properties of the Cr-C system were determined by means of emf measurements using a single crystal of calcium fluoride as a solid electrolyte. The constructions of fluorine concentration cells were
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Using the emf values and its temperature dependences of the above cells between 880° and 1098°K, the standard free energies and enthalpies of formation of Cr3C2 and Cr7C3 were obtained as
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