JJAP Conference Proceedings
Online ISSN : 2758-2450
Asia-Pacific Conference on Semiconducting Silicides and Related Materials - Science and Technology Towards Sustainable Electronics (APAC Silicide 2016)
Session ID : 011201
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Photovltaic materials
Realization of crystalline BaSi2 thin films by vacuum evaporation on (111)-oriented Si layers fabricated by aluminum induced crystallization
Jefferson A. WibowoIsao TakahashiKosuke O. HaraNoritaka Usami
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Abstract

We have realized single phase crystalline BaSi2 thin films on quartz substrate by vacuum evaporation for solar cell applications. This structure is achieved by introducing (111)-oriented poly-Si fabricated by aluminum induced crystallization as a supply layer prior to BaSi2 deposition. Raman measurements showed five characteristic peaks corresponding to [Si4]4− anions vibrations in BaSi2 for all films deposited at 400 °C and above. X-ray diffraction analysis showed that randomly-oriented orthorhombic phase of BaSi2 is achieved with no trace of secondary phases. Also, the crystal quality is enhanced at higher substrate temperatures.

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