エネルギー・資源学会論文誌
Online ISSN : 2433-0531
ISSN-L : 2433-0531
研究論文
ジメチルエーテルを用いた排熱の熱回生プロセスにおける反応速度評価
鬼頭 毅大坂 侑吾小林 敬幸中川 二彦
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ジャーナル フリー

2011 年 32 巻 1 号 p. 16-21

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For the new process of effective utilization of energy, the process of recovery of exhaust heat energy with steam reforming of dimethyle ether (DME) proposed. Steam reforming of DME is an endothermic reaction as; DME + 3H2O+122[KJ/mol] → 6H2O +2CO2-122.5KJ/mol.So,if the exhaust heat energy would be used for the reforming reaction, the exhaust heat energy could be recovered as hydrogen, fuels of high quality. In this study, Fundamental experiment for steam reforming of DME has been done with fixed bed reactor, changing experimental condition; W/F, temperature, H2O partial pressure and DME partial pressure. Reaction rate equation was formulated with experimental results. DME conversion with the obtained equation and DME conversion with experiment was average error with 0.04[-]. Next, Quantity of catalyst for reactor was compared with device scale of exhaust heat source; gas engine with reaction rate equation obtained. Quantity of catalyst was fully smaller by comparing to device scale of exhaust heat source.
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© 2011 一般社団法人エネルギー・資源学会
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