Journal of the Japan Society of Powder and Powder Metallurgy
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
Paper
Effect of Two-dimensional Vacancy Planes on the Thermal and Electrical Transport Properties of TiO2-x
Tomohisa YamamotoYuji OhishiKen KurosakiHiroaki MutaShinsuke Yamanaka
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JOURNAL OPEN ACCESS

2012 Volume 59 Issue 4 Pages 196-200

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Abstract
The effect of the planar defects on the electrical transport properties was investigated in the non-stoichiometric titanium oxide; TiO2-x. TiO2-x with rutile structure is known to have a semiconductor property and planar periodic structure with lattice defects of oxygen vacancies. TiO2-x with point defects and planar defects are synthesized by the reduction of TiO2 and the oxidation of TiO. The defects structure was estimated from the powder XRD patterns. The thermal conductivities were measured using laser flash technique. The electrical properties were measured using the van der Pauw method. The TiO2-x with planar defects showed lower thermal conductivity than those with point defects. In contrast, the TiO2-x with planar defects showed slightly higher carrier nobilities than those with point defects.
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© 2012 by Japan Society of Powder and Powder Metallurgy

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