粉体および粉末冶金
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
酸化タングステンの水素還元の研究 第一報 タングステン粒子に就いて
佐々木 申二上田 隆三
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ジャーナル オープンアクセス

1949 年 3 巻 1 号 p. 1-7

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Microscopic observation revealed that the reduction product of a single piece of WO3 crystal is consisted of about 0.5μ. particles, or primary particles, which are single crystals of metal formed by the atomic sintering of W atoms produced by the reduction. If the oxide crystal lying flat on a supporting surface is reduced, these primary particles remain scattered on the substratum, marking the exact contour of the original oxide crystal. But, if reduced in a free space, they loosely stick together to form an aggregate, or a secondary particle, which retains the original shape with about 30 per cent contraction. If a mass of WO3 crystals are reduced, secondary particles may loosely cling together to form tertiary particles and so on.
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© 社団法人粉体粉末冶金協会

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