アルミナ粒径及びフラックスの比表面積がグリーンシートの粉体充填率に及ぼす影響

抄録

We studied the effects of alumina particle diameter and flux specific surface area on the powder packing density of green sheet. When the alumina particle diameter was in the range 0.8 to 3.6pm and the flux specific surface area was 1 to 20 m²/g, the packing density was 61 vol%, nearly the same as the theoretical packing density (60.45 vol%) of monosized powder of single stagger arrangement.
However, the packing density decreased to 60 vol% when the particle diameter was 0.5μm. It also decreased to 55 vol% or to 38% when the flux specific surface area was 100 m²/g, or 380 m2/g, as for alumina/ flux powder mixture, the larger the alumina particle diamater and the smaller the flux specific surface area, the higher became the packing density. The packing density of alumina green sheet remained unchanged (61 vol%) even when the amount of binder varied within the range 3 to 18 weight%. When the amount of binder was more than 18 weight%, the packing density decreased linearly as the amount of binder increased, regardless of whether the binder was polyvinyl butyral or polymethylmetacryrat.