抄録
The formation process and magnetic properties of Fe3C particles were investigated. Various iron oxides as a starting material were carbureted with CO gas in a furnace. Fe3C was formed at the reaction temperatures from 450 to 600°C. The partial pressure of CO gas was controlled by mixing with N2 gas to prevent the free carbon deposition due to the disproportionation of CO gas. Synthesized Fe3C particles were identified as a single phase by XRD and the weight change measurement. The saturation magnetization of Fe3C increased from 80 to 117 emu/g with the increase of the reaction temperature, while the coercive force decreased from 170 to 80 Oe with the increase of the reaction temperature.