Abstract
We studied the effects of adding Ca to the Bi2+xSr2-xCu1+x/4Oz solid solution. It turned out that the Ca ions substitute for Sr. Monopasic compositions of Bi2+xSr2-x-yCayCu1+x/4 with 0.1<x<0.6 and 0<y<0.6 were obtaind. In the Ca-containing solid solution. The specimen of Bi2.1Sr1.8⋅Ca0.1Cu1.025Oz showed superconductivity at 7.8K. But the others were semiconductive.