粉体および粉末冶金
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
YBa2Cu3O7-xの臨界温度に及ぼす焼成雰囲気中の水蒸気分圧の効果
鈴木 建次神阪 直志香山 滉一郎
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ジャーナル オープンアクセス

1993 年 40 巻 5 号 p. 550-555

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抄録
The effect of water vapor in a calcining atomosphere on Tc, off of YBa2Cu3O7-x was investigated using the electrical resistivity method, X-ray diffraction analysis and carbon analysis. The results are as follows:
(1) The critical temperature(To, off) elevated with increasing H2O partial pressure, reached a maximum(90.5K) at a H2O partial pressure of about 5kPa, and then lowered.
(2) The water vapor remarkably accelerated the decomposition of BaCO3. However, the excessive addition of water vapor was detrimental because of the formation of an unknown phase.
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