Luminescence Characteristics of Ni2+ Ion-Doped Glasses and Glass-Ceramics in Relation to Its Coordination Number

Sasithorn KHONTHON; Shigeki MORIMOTO; Yasutake OHISHI

doi:10.1299/jmmp.1.439

Papers

Luminescence Characteristics of Ni2+ Ion-Doped Glasses and Glass-Ceramics in Relation to Its Coordination Number

Sasithorn KHONTHON, Shigeki MORIMOTO, Yasutake OHISHI

著者情報

キーワード: Ni²⁺ Ion, Transparent Glass-Ceramics, Absorption Spectra, UV-VIS-NIR Emission Spectra, Coordination Number

ジャーナルフリー

2007 年 1 巻 4 号 p. 439-446

DOI https://doi.org/10.1299/jmmp.1.439

詳細

抄録

Ni²⁺ ions occupy the tetrahedral (4), trigonal bipyramid (5) and octahedral (6) sites in glasses and glass-ceramics. The color changes depending on coordination number, typically pink for tetrahedral site, brown for trigonal bipyramid and tetrahedral sites and green to blue for octahedral site, respectively. The broad near infrared (NIR) emission peaking at around 1220 nm was observed for octahedral Ni²⁺ ions. This emission is due to ³T₂(F)→³A₂(F) transition.

責任著者(Corresponding author)

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