Journal of Japan Oil Chemists' Society
Online ISSN : 1884-2003
ISSN-L : 0513-398X
Preparation of Oxides, Glycols and Polyglycols from Lower Olefines. III.
Preparation of Propylene Glycols
Hajime TOKUNOHiroaki YAMAMOTOMasataka TSUTOMI
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1961 Volume 10 Issue 11 Pages 688-693

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Abstract
The authors contemplated to manufacture propylene glycol by catalytic and high pressure process.
In the high pressure procss, it was found that impurities contained in the propylene oxide have acidified the crude propylene glycol solution.
In the catalytic process, the optimum catalyst concentration was at 0.02%.
For continuous catalytic hydrolysis of propylene oxide to propylene glycol, using a multi-type reactor, four vessels were required to complete the reaction, and the catalyst was completely neutralized with alkali within 30 minutes at 90°C.
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