Journal of Japan Oil Chemists' Society
Online ISSN : 1884-2003
ISSN-L : 0513-398X
Studies on the Activity and Selectivity of the Copper-Chromium-Manganese Oxide Catalyst. IX.
On the Hydrogenation of the Small Amount of Acetylene contained in Ethylene with the Copper-Chromium-Manganese Catalyst
Shizuo TAKUMIToshio HASHIMOTOFumio TAKEI
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1961 Volume 10 Issue 9 Pages 568-572

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Abstract

An experiment has been made on the hydrogenation of acetylene contained in a small amount in ethylene with the copper-chromium-manganese oxide catalyst.
It was proved that the catalyst has good selectivity, as follows :
Hydrogenation of ethylene has scarcely occurred until almost all the acetylene contained in ethylene has been hydrogenated to ethylene. But, when ethylene contains absolutely no acetylene, hydrogenation of ethylene occurs quite easily.
Optimum operation conditions are as follows :
Temperature : 200°C; S.V. : 1000; Ratio of hydrogen to acetylene : 2 : 1

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