Journal of Japan Oil Chemists' Society
Online ISSN : 1884-2003
ISSN-L : 0513-398X
Condensation of Octene-2 with Formaldehyde
Choichiro HIRAIMichisuke NARAKITaro MATSUMOTO
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1964 Volume 13 Issue 8 Pages 413-418

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Abstract
In the previous report, authors studied the acid catalyzed condensation of octadecene-1 with formaldehyde in acetic acid, and the products were 4-hexadecyl-1, 3-dioxane, 3-pentadecyl-4-hydroxytetrahydropyrane and nonadecadiol-1, 3, respectively.
In this paper, authors investigated the simillar reaction of octene-2 with formaldehyde.
The reaction products were saponified and fractionated mainly by chromathography and following substances were separated.
The characteristics of these substances were identified to those of 4-methyl-5-pentyl-1, 3-dioxane, 3-penthyl-4-hydroxytetrahydropyrane and 2-pentyl-3-hydroxybutanol-1, respectively.
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