Journal of Japan Oil Chemists' Society
Online ISSN : 1884-2003
ISSN-L : 0513-398X
Synthesis of Di- (D-glucose) Dicarboxylate
Yasuo NISHIZAWANorito UCHINOSeishi MACHIDA
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1966 Volume 15 Issue 3 Pages 108-111

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Abstract
Di- (1, 2 : 5, 6-diisopropylidene-D-glucose) dicarboxylate was prepared from 1, 2 : 5, 6-diisopropylidene-D-glucose and dimethyl ester of dibasic acid (i.e. adipic, pimelic azelaic and sebacic), by transesterification in dimethylformamide. The same ester was also obtained by acylation of 1, 2 : 5, 6-diisopropylidene-D-glucose with the chloride of the above dibasic acid.
The ester thus obtained was converted into di- (D-glucose) dicarboxylate by sulfuric acid. After evaluation studies, a fairly promising emusifying property was found for the latter ester.
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