Abstract
Chlorophosphonation of some acid chlorides was carried out under the condition of the mole ratio of acid chloride to PCl3 1 : 5, the flow rate of oxygen 200ml/min, the temperature -2010°C, and the reaction time for 3hrs. The compositions of the products, esterified with ethanol, were identified by GLC (Ucon LB 550 X, 203226°C, N2 gas carrier) in comparision with authentic samples synthesized by other methods. The product distribution (mol%) in chlorophosphonation of acid chlorides is as follows.
