Journal of Japan Oil Chemists' Society
Online ISSN : 1884-2003
ISSN-L : 0513-398X
The Reaction of Fatty Acids with Vinylmagnesium Chloride
Kyoichi SUGAShoji WATANABETsutomu FUJITAYukio TAKAHASHI
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JOURNAL FREE ACCESS

1972 Volume 21 Issue 1 Pages 29-32

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Abstract
The reaction of vinylmagnesium chloride with various fatty acids gives a mixture of new unsaturated ketone and divinyl alkyl carbinol. For example, from n-butyric acid, a mixture of 3-n-propyl-3-hydroxyl-1, 4-pentadiene and 5-oxo-1-octene was obtained in a total yield of 64%. Similarly, a mixture of unsaturated ketone and divinyl carbinol was obtained from other fatty acids.
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