Journal of Japan Oil Chemists' Society
Online ISSN : 1884-2003
ISSN-L : 0513-398X
Analysis of Trimethylsilyl Ethers of Diols with Gas Chromatograph-Mass Spectrometer
Kiyozo HASEGAWAMichiyo MURATATetsuya SUZUKI
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1972 Volume 21 Issue 7 Pages 383-386

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Abstract
Mass spectra of trimethylsilyl ethers of ethylene glycol, propane-1, 2-diol, butane-2, 3-diol (meso), propane-1, 3-diol, butane-1, 3-diol, butane-1, 4-diol, pentane-1, 5-diol and glycerol were obtained by GC-MS method. The base peak ions of these mass spectra were at m/e 147 in the ethers except those of butane-2, 3-diol and glycerol, which were observed at m/e 117 and 205 respectively. Other features of the spectra were discussed in relation to the molecular weight and structure. GC-MS method was useful for identification of the ethers.
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