Journal of Japan Oil Chemists' Society
Online ISSN : 1884-2003
ISSN-L : 0513-398X
Reaction of Amines and Their Utilization. III.
Studies on the Cyclization of Long Chain N-Acylethylenediamines
Masayoshi KITAYutaka YAMADA
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1975 Volume 24 Issue 2 Pages 112-115

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Abstract
Authors found that N-acylethylenediamines obtained by the reactions of the methyl esters of C812 fatty acids with ethylenediamine readily cyclizes on heating to yield 2-alkyl 4, 5-dihydroimidazoles. The following results were also obtained with this finding.
The type of the principal product obtained from the reaction between the methyl ester of a fatty acid with ethylenediamine in ethanol was dependent on the method of separation of the reaction product; namely, the solvent extraction afforded the N-acylethylenediamine and the distillation under reduced pressure afforded 2-alkyl-4, 5-dihydroimidazol.
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